Reputable factory supply 3-HYDROXY-2-METHYL-CYCLOPENT-2-ENONE 5870-63-3 in stock with high standard
- Molecular Formula: C6H8 O2
- Molecular Weight: 112.128
- Melting Point: 213-215 °C(Solv: ethanol (64-17-5))
- Boiling Point: 212.2°Cat760mmHg
- PKA: 4.82±0.30(Predicted)
- Flash Point: 84.4°C
- PSA: 37.30000
- Density: 1.225g/cm3
- LogP: 1.18130
5870-63-3 Relevant articles
Conversion of cycloalk-2-enones into 2-methylcycloalkane-1,3-diones - Assessment of various Tamao-Fleming procedures and mechanistic insight into the use of the Me3SiMe2Si unit
Yu, Guojun,Clive, Derrick L. J.
, p. 1653 - 1664 (2016/02/10)
Conjugate addition of Me3SiMe2SiLi to cy...
Reactions of 1,2-bis(trimethylsilyloxy)cycloalkenes with the diethyl acetals of aldehydes
Gao, Fuye,Burnell, D. Jean
, p. 356 - 359 (2007/10/03)
Lewis acid-mediated reactions of 1,2-bis...
5870-63-3 Process route
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54972-03-1
2-methylcyclopentane-1,3-dione ethylene glycol monoacetal
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5870-63-3
3-hydroxy-2-methyl-2-cyclopenten-1-one
| Conditions | Yield |
|---|---|
|
With
hydrogenchloride;
In
tetrahydrofuran; water;
for 10h;
|
71%
|
-
-
930-30-3
cyclopent-2-enone
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-
5870-63-3
3-hydroxy-2-methyl-2-cyclopenten-1-one
| Conditions | Yield |
|---|---|
|
Multi-step reaction
with
5
steps
1.1: N,N,N,N,N,N-hexamethylphosphoric triamide; methyllithium / diethyl ether / 0.5 h / 0 °C / Inert atmosphere
1.2: 1 h / -78 °C / Inert atmosphere
1.3: 3 h / -78 - 20 °C / Inert atmosphere
2.1: toluene-4-sulfonic acid / benzene / 6 h / Reflux; Dean-Stark
3.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 0.33 h / Inert atmosphere
3.2: 20 h
4.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / dichloromethane / 0.5 h / Molecular sieve; Inert atmosphere
5.1: hydrogenchloride / tetrahydrofuran; water / 10 h
With
hydrogenchloride; N,N,N,N,N,N-hexamethylphosphoric triamide; tetrapropylammonium perruthennate; tetrabutyl ammonium fluoride; methyllithium; toluene-4-sulfonic acid; 4-methylmorpholine N-oxide;
In
tetrahydrofuran; diethyl ether; dichloromethane; water; benzene;
3.2: |Tamao-Kumada Oxidation;
|
5870-63-3 Upstream products
-
930-30-3
cyclopent-2-enone
-
54972-03-1
2-methylcyclopentane-1,3-dione ethylene glycol monoacetal
5870-63-3 Downstream products
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3883-56-5
3-methoxy-2-methylcyclopent-2-enone
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72302-65-9
2-methyl-2-(phenylthio)-1,3-cyclopentanedione
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25112-86-1
2-Methylcyclopent-1,3-dione monoethyl enol ether
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118824-28-5
3-(4-phenylselenobutanoxy)-2-methylcyclopent-2-en-1-one