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Cosmetics Grade 4-Methoxycyclohexanon 13482-23-0 For Sale with Good Price
- Molecular Formula: C7H12O2
- Molecular Weight: 128.171
- Vapor Pressure: 0.574mmHg at 25°C
- Refractive Index: 1.4560
- Boiling Point: 189.279 °C at 760 mmHg
- Flash Point: 68.844 °C
- PSA： 26.30000
- Density: 0.988 g/cm3
- LogP: 1.14450
4-Methoxycyclohexanon(Cas 13482-23-0) Usage
InChI:InChI=1/C7H12O2/c1-9-7-4-2-6(8)3-5-7/h7H,2-5H2,1H3
13482-23-0 Relevant articles
Ammonium Tungstate as an Effective Catalyst for Selective Oxidation of Alcohols to Aldehydes or Ketones with Hydrogen Peroxide under Water - A Synergy of Graphene Oxide
Fu, Huihui,Hu, Chuanfeng,Huang, Zhida,Zhou, Jianhao,Peng, Xinhua
, p. 447 - 451 (2018)
Ammonium tungstate was found to be a fac...
-
Baldry,K.W. et al.
, p. 2589 - 2594 (1976)
-
Synthesis method of 4-substituent cyclohexanone
-
Paragraph 0034; 0036-0037; 0042-0045, (2021/05/12)
The invention discloses a synthesis meth...
Synthesis method of 4-substituent cyclohexanone liquid crystal intermediate
-
Paragraph 0048; 0050-0051, (2021/05/19)
The invention discloses a synthesis meth...
POLITAG-Pd(0) catalyzed continuous flow hydrogenation of lignin-derived phenolic compounds using sodium formate as a safe H-source
Campana, Filippo,Ferlin, Francesco,Silvetti, Matteo,Trombettoni, Valeria,Vaccaro, Luigi,Valentini, Federica
, (2021/07/09)
Phenols are aromatic biobased compounds ...
Highly Selective Hydrogenation of Phenols to Cyclohexanone Derivatives Using a Palladium@N-Doped Carbon/SiO2Catalyst
Sheng, Xueru,Wang, Chao,Wang, Wentao
supporting information, p. 2425 - 2431 (2021/11/16)
A new palladium-based heterogeneous mate...
13482-23-0 Process route
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150-76-5
4-methoxy-phenol
-
-
13482-23-0
4-methoxycyclohexanone
-
-
108-94-1,11119-77-0,9003-41-2,9075-99-4
cyclohexanone
| Conditions | Yield |
|---|---|
|
With
potassium tetrachloropalladate(II); dodecatungstophosphoric acid hydrate; hydrogen;
In
water;
at 100 ℃;
for 18h;
under 1500.15 Torr;
|
|
|
With
sodium formate;
In
water;
at 80 ℃;
for 18h;
chemoselective reaction;
Sealed tube;
|
-
-
4746-97-8
cyclohexanedione monoethylene ketal
-
-
13482-23-0
4-methoxycyclohexanone
| Conditions | Yield |
|---|---|
|
Multi-step reaction
with
3
steps
1: 98 percent / sodium borohydride / methanol / 1 h
2: sodium hydride
3: 0.92 g / HCl / acetone
With
hydrogenchloride; sodium tetrahydroborate; sodium hydride;
In
methanol; acetone;
|
|
|
Multi-step reaction
with
3
steps
1.1: sodium tetrahydroborate / methanol / 3 h / 0 - 20 °C / Inert atmosphere
1.2: 20 °C / Inert atmosphere
2.1: potassium hydride / tetrahydrofuran / 0.52 h / -16 - 20 °C / Inert atmosphere
2.2: 48 h / 20 °C / Inert atmosphere
3.1: hydrogenchloride / tetrahydrofuran; water / 0.5 h / Inert atmosphere; Reflux
With
hydrogenchloride; sodium tetrahydroborate; potassium hydride;
In
tetrahydrofuran; methanol; water;
|
|
|
Multi-step reaction
with
3
steps
1.1: sodium tetrahydroborate; methanol / 2 h / 20 °C
2.1: sodium hydride / tetrahydrofuran / 0.17 h / 20 °C
2.2: 3 h
3.1: toluene-4-sulfonic acid; water / tetrahydrofuran / 100 °C
With
methanol; sodium tetrahydroborate; water; sodium hydride; toluene-4-sulfonic acid;
In
tetrahydrofuran;
|
|
|
Multi-step reaction
with
3
steps
1: sodium tetrahydroborate / methanol / 3 h / 0 - 20 °C
2: sodium hydride / tetrahydrofuran; mineral oil / 17 h / 0 - 20 °C
3: hydrogenchloride / water; tetrahydrofuran / 0.5 h / Reflux
With
hydrogenchloride; sodium tetrahydroborate; sodium hydride;
In
tetrahydrofuran; methanol; water; mineral oil;
|
|
|
Multi-step reaction
with
3
steps
1.1: sodium tetrahydroborate / methanol / 16 h / 20 °C / Inert atmosphere
2.1: sodium hydride / tetrahydrofuran; N,N-dimethyl-formamide; mineral oil / 1 h / 0 - 50 °C / Inert atmosphere
2.2: 16 h / 0 - 50 °C / Inert atmosphere
3.1: iron(III) chloride hexahydrate / dichloromethane / 3 h / 20 °C
With
sodium tetrahydroborate; iron(III) chloride hexahydrate; sodium hydride;
In
tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide; mineral oil;
|
|
|
Multi-step reaction
with
3
steps
1.1: sodium tetrahydroborate / methanol / 12 h / 0 - 20 °C
2.1: sodium hydride / tetrahydrofuran / 1 h / 0 °C
2.2: 12 h / Reflux
3.1: toluene-4-sulfonic acid / water / 1 h / 100 °C
With
sodium tetrahydroborate; sodium hydride; toluene-4-sulfonic acid;
In
tetrahydrofuran; methanol; water;
|
|
|
Multi-step reaction
with
3
steps
1: sodium tetrahydroborate / ethanol / 1 h / 0 - 20 °C
2: sodium hydride / N,N-dimethyl-formamide / 2.17 h / 0 - 20 °C
3: hydrogenchloride / tetrahydrofuran; water / 20 °C
With
hydrogenchloride; sodium tetrahydroborate; sodium hydride;
In
tetrahydrofuran; ethanol; water; N,N-dimethyl-formamide;
|
|
|
Multi-step reaction
with
3
steps
1.1: sodium tetrahydroborate / 3 h / 0 - 20 °C
2.1: sodium hydride / 1 h / 40 °C
2.2: 16 h / 20 - 50 °C
3.1: toluene-4-sulfonic acid / water; acetone / 16 h / Heating / reflux
With
sodium tetrahydroborate; sodium hydride; toluene-4-sulfonic acid;
In
water; acetone;
|
|
|
Multi-step reaction
with
3
steps
1.1: sodium tetrahydroborate / ethanol / 1 h / 0 - 20 °C
2.1: sodium hydride / N,N-dimethyl-formamide / 0.17 h / 0 °C
2.2: 2 h / 20 °C
3.1: hydrogenchloride; water / tetrahydrofuran / 20 °C
With
hydrogenchloride; sodium tetrahydroborate; water; sodium hydride;
In
tetrahydrofuran; ethanol; N,N-dimethyl-formamide;
|
13482-23-0 Upstream products
-
4746-97-8
cyclohexanedione monoethylene ketal
-
150-76-5
4-methoxy-phenol
-
556-48-9
1,4-Cyclohexanediol
-
18068-06-9
4-methoxycyclohexan-1-ol
13482-23-0 Downstream products
-
111529-78-3
(+/-)-2-((E )-2-cyclohexyliden-ethylidene)-4-methoxy-cyclohexanone
-
102878-81-9
4-methoxy-1-methylcyclohexan-1-ol
-
102195-49-3
1-ethynyl-4-methoxycyclohexan-1-ol
-
98959-49-0
(4-methoxy-cyclohex-1-enyl)-acetonitrile
